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Original Articles

Vol. 5 No. 1 (2026)

Eco-Friendly Adsorbents for Removal of Heavy Metals and Rhodamine B Using Activated Rice Husk, Coconut Shell and Modified Clay

Published
2026-05-27

Abstract

Access to clean and safe drinking water requires effective filtration technologies. In the recent past, green adsorbents have gained attention as sustainable alternatives to conventional ones because they are derived from abundant, renewable, and naturally occurring materials or waste products. This study, therefore, investigated the preparation and application of activated rice husk charcoal (ARC), activated coconut shell charcoal (ACC), and acid-modified clay soil (ACS) as biosorbents for the removal of Co²⁺, Cu²⁺, Pb²⁺ ions, and rhodamine B (RB) dye from water. The adsorbents were characterized using FTIR, XRD, XRF, TEM, and BET before adsorption studies. Batch experiments were conducted to evaluate the effects of solution pH, temperature, contact time, particle size, and adsorbent dosage. Residual metal concentrations were quantified using Atomic Absorption Spectroscopy (AAS), achieving maximum removal efficiencies of 95%, 93% and 90% in ARC, 93%, 89% and 86% in ACC and 87%, 86% and 81% in ACS for Pb2+, Cu2+ and Co2+, respectively. For RB, 93%, 89% and 85% were achieved correspondingly by ARC, ACC and ACS, implying highest adsorption efficiency exhibited by ARC under the studied conditions. Metal ions removal was optimal at pH 6, whereas RB dye was highly adsorbed at pH 4. Overall, ARC, ACC, and ACS demonstrated significant potential as eco-friendly adsorbents for the elimination of heavy metals and dyes from wastewater.

References

  1. Abdulredha, M., Rafid, A., Jordan, D. and Hashim, K. (2017). The development of a waste management system in Kerbala during major pilgrimage events: determination of solid waste composition. Procedia Engineering; 196: 779–784. https://doi.org/10.1016/j.proeng.2017.08.007
  2. Afroze, S., Sen, T.K. and Ang, H.M. (2016). Adsorption removal of zinc (II) from aqueous phase by raw and base modified Eucalyptus sheathiana bark: Kinetics, mechanism and equilibrium study. Process Safety and Environmental Protection, 102: 336-352. https://www.sciencedirect.com/science/article/abs/pii/S095758201630026X
  3. Al-Hashimi, O., Hashim, K., Loffill, E., Marolt, C. T., Nakouti, I., Faisal, A. A. and Al-Ansari, N. (2021). A comprehensive review for groundwater contamination and remediation: occurrence, migration and adsorption modelling. Molecules; 26(19):5913. https://doi.org/10.3390/molecules26195913
  4. Al-Sareji, O. J., Grmasha, R. A., Salman, J. M., Idowu, I. and Hashim, K. S. (2021). Street dust contamination by heavy metals in Babylon governorate, Iraq. Journal of Engineering Science and Technology; 16(1):3528–3546. https://researchonline.ljmu.ac.uk/id/eprint/17033/
  5. Argun, M. E., Dursun, S., Ozdemir, C., and Karatas, M. (2006). Heavy metal adsorption by modified oak sawdust: Thermodynamics and kinetics. Journal of Hazardous Materials, 141, 77–85. https://doi.org/10.1016/j.jhazmat.2006.06.095
  6. Bakti, A. I. and Gareso, P. L. (2018). Characterization of Active Carbon Prepared from Coconuts Shells Using FTIR, XRD and SEM Techniques. Jurnal ilmiah pendidikan fsika Al-Biruni 7:33-39. https://ejournal.radenintan.ac.id/index.php/al-biruni/article/view/2459
  7. Bao, J., Feng,Y., Pan,Y. and Jiang, J. (2024). Adsorption of Co2+ and Cr3+ in Industrial. Wastewater by Magnesium Silicate Nanomaterials. Materials, 17(9): 1746. https://www.mdpi.com/1996-1944/17/9/1946
  8. Chengo, K., Murungi, J. and Mbuvi, H. (2013). Speciation of Zinc and Copper in Open-Air Automobile Mechanic Workshop Soils in Ngara Area-Nairobi Kenya. Resources and Environment, 3: 145-154.
  9. Ewecharoena, A., Thiravetyana, P. and Bertagnollib, H. (2009). Nickel adsorption by sodium polyacrylate-grafted activated carbon. J. Haar. Mat; 171:335-339. https://doi.org/10.1016/j.jhazmat.2009.06.008
  10. Fu, F. and Wang, Q. (2011). Removal of heavy metal ions from wastewaters: A review. Journal of Environmental Management, 92, 407–418. https://doi.org/10.1016/j.jenvman.2010.11.011
  11. Ghanadzadeh, A., Zanjanchi, M.A. and Tirbandpay, R. (2002). The role of host environment on the aggregative properties of some ionic dye materials, J. Mol. Struct. 616: 167-174. https://www.sciencedirect.com/science/article/abs/pii/S0022286002003241
  12. Gong, R., Ding, Y., Liu, H., Chen, Q. and Liu, Z. (2005). Lead biosorption by intact and pretreated Spirulina maxima biomass. Chemosphere, 58: 125-130. https://doi.org/10.1016/j.chemosphere.2004.08.055
  13. Gupta N, Kushwaha AK, Chattopadhyaya, M. C. (2012). Adsorption studies of cationic dyes onto Ashoka (Saraca asoca) leaf powder. J. Taiwan Inst Chem Eng, 43:604–613. https://doi.org/10.1016/j.jtice.2012.01.008
  14. Hui, K. S., Chao, C. Y. H., and Kot, S. C. (2005). Removal of mixed heavy metal ions in wastewater by zeolite and residual products from recycled coal fly ash. Journal of Hazardous Materials, 127: 89–101. https://doi.org/10.1016/j.jhazmat.2005.06.027
  15. Irannajad, M. and Haghighi, H. K. (2017). Removal of Co2+, Ni2+ and Pb2+ by manganese oxide-coated zeolite: Thermodynamics and kinetic studies. Clays and clay minerals. 65: 52-62. https://www.cambridge.org/core/journals/clays-and-clay-minerals/article/abs/removal-of-co2-ni2-and-pb2-by-manganese-oxidecoated-zeolite-equilibrium-thermodynamics-and-kinetics-studies/C27423F17872D43F833414894400F667
  16. Katircioğlu, H., Aslim, B., Türker, R. A., Atici, T., and Beyatli, Y. (2008). Removal of cadmium(II) ion from aqueous system by dry biomass, immobilized live and heat inactivated Oscillatoria sp. H1 isolated from freshwater (Mogan Lake). Bioresource Technology, 99: 4185–4191. https://www.sciencedirect.com/science/article/abs/pii/S0960852407007316
  17. Khan, A., Naqvi, H. J., Afzal, S., and Jabeen, S. (2017). Efficiency Enhancement of Banana Peel for Waste Water Treatment through Chemical Adsorption. Academy of Sciences: A. Physical and Computational Sciences, 54(3), 329–335. http://ppaspk.org/index.php/PPAS-A/article/view/230
  18. Kobya, M., Demirbas, E., Senturk, E., Ince, M. (2005). Adsorption of heavy metal ions from aqueous solutions by activated carbon prepared from apricot stone, Bioresource Technology, 96 13, 1518–1521. https://www.sciencedirect.com/science/article/abs/pii/S0960852405000039
  19. Levin, R., Brown, M. J., Kashtock, M. E., Jacobs, D. E., Whelan, E. A., Rodman, J., and Sinks, T. (2008). Lead exposures in US children, 2008: implications for prevention. Environmental Health Perspectives, 116: 1285. https://doi.org/10.1289/ehp.11241
  20. Manyangadze, M., Chikuruwo, N. M. H., Narsaiah, T. B., Chakra, C. S., Charis, G., Danha, G., and Tirivaviri, A. M. (2020). Adsorption of lead ions from wastewater using nano silica spheres synthesized on calcium carbonate templates. Heliyon, 6(11): 1–13. https://www.cell.com/heliyon/fulltext/S2405-8440(20)32152-6
  21. Mousavi, H. Z., Hosseynifar, A., Jahed, V. and Dehghani, S. A. (2010). Removal of Lead from Aqueous Solution using Waste Tire Rubber Ash as an Adsorbent. Brazilian Journal of Chemical Engineering, 27(01): 79–87. https://www.scielo.br/j/bjce/a/9fjbLB3Yg7hHJKXjkhnsxQS/?format=html&lang=en
  22. Muiruri, J., Nyambaka, H. and Ngwiri, M. (2013). Heavy metals in water & tilapia from Athi Galana-sabaki tributaries Kenya. International Food Research Journal, 20: 891-896. https://ir-library.ku.ac.ke/server/api/core/bitstreams/8cd6bb63-cadc-4b8e-b9f9-9b5ea553d3f9/content
  23. Muller, B. R. (2010). Effect of particle size and surface area on the adsorption of albumin- bonded bilirubin on activated carbon. Elsevier, 48: 3607-3615. https://www.sciencedirect.com/science/article/abs/pii/S0008622310004045
  24. Mustapha, S., Shuaib, D. T., Ndamitso, M. M., Etsuyankpa, M. B., Sumaila, A., Mohammed, U. M., & Nasirudeen, M. B. (2019). Adsorption isotherm, kinetic and thermodynamic studies for the removal of Pb (II), Cd (II), Zn (II) and Cu (II) ions from aqueous solutions using Albizia lebbeck pods. Applied water science, 9(6), 142.
  25. Naja, G., Mustin, C., Berthelin, J. and Volesky, B. (2010). Lead biosorption study with Rhizopus arrhizus using a metal-based titration technique. J Colloid and Interface Science. 292(2):537–543. https://doi.org/10.1016/j.jcis.2005.05.098
  26. Ngah, W.W. and Hanafiah, M. M. (2008). Removal of heavy metal ions from wastewater by chemically modified plant
  27. wastes as adsorbents: a review. Bioresource technology; 99(10): 3935–3948. https://doi.org/10.1016/j.biortech.2007.06.011
  28. Pang, T., Yang Z., Huang, Y., Lei, X., Zeng, X., Li, X. (2018). Adsorption Properties of Thiol Modified, Sodium-Modified and Acidified Bentonite for Cu2+, Pb2+ and Zn2+ Spectrosc. Spectr. Anal. 38:1203–1208.
  29. Rahmati, A., Ghaemi, A. and Samadfam, M. (2012). Kinetic and Thermodynamic studies of Uranium(VI) Adsorption Using Amberlite IRA-910 Resin. Annals of Nuclear Energy. 39: 42-48. https://doi.org/10.1016/j.anucene.2011.09.006
  30. Salah, Z. L., Gharghan, S. K., Dooley, J., Alkhaddar, R. M. and Abdellatif, M. (2018). Short term urban water demand prediction considering weather factors. Water Resource Management; 32(14): 4527–4542. https://link.springer.com/article/10.1007/s11269-018-2061-y
  31. Sheta, A., Falatah, M., Sewailem, S., Khaled, E. and Sallam, H. (2003). Sorption characteristics of zinc and iron by natural zeolite and bentonite. Microporous Material, 61: 127-136. https://doi.org/10.1016/S1387-1811(03)00360-3
  32. Srivastava, V., Shekhar, M., Gusain, D., Gode, F., and Sharma, Y. C. (2017). Application of a heterogeneous adsorbent (HA) for the removal of hexavalent chromium from aqueous solutions: Kinetic and equilibrium modeling. Arabian Journal of Chemistry, 10: 1–26. https://www.sciencedirect.com/science/article/pii/S187853521300419X
  33. Tong, S., Schirnding, Y., Von, E. and Prapamontol, T. (2000). Environmental lead exposure: a public health problem of global dimensions. Bulletin of the World Health Organization, 9: 1068-1077. https://www.scielosp.org/pdf/bwho/v78n9/v78n9a03.pdf
  34. Ugwu, E. I., Tursunov, O., Kodirov, D., Shaker, L. M., Al-Amiery, A. A., Yangibaeva, I. and Shavkarov, F. (2020). Adsorption mechanisms for heavy metal removal using low cost adsorbents: A review. IOP Conference Series: Earth and Environmental Science, 614(1): 1–13.
  35. Vieira, M. G. A., De-Almeida, N. A. F., Da-Silva, M. G. C., Carneiro, C. N. and Melo, F. A. (2013). Adsorption of Lead and Copper Ions from Aqueous Effluents on Rice Husk Ash in a Dynamic System. Brazilian Journal of Chemical Engineering, 31(2):519 – 529. https://www.scielo.br/j/bjce/a/PHmwC7VKH6xFnpWMG4rDv8k/?lang=en
  36. Wang, H. and Shadman, F. (2013). Effect of particle size on the adsorption properties of oxide nanoparticles. American institute of chemical engineers, 59(5): 1502-1510. https://doi.org/10.1002/aic.13936
  37. Winter, M. & Brodd, R. J. (2004). What Are Batteries, Fuel Cells, and Supercapacitors? Chem. Rev. 104: 4245–4270. https://pubs.acs.org/doi/full/10.1021/cr020730k
  38. Yagub, M. T., Sen, T. K., Afroze, S. and Ang, H. M. (2014). Dye and its removal from aqueous solution by adsorption: a review. Advances in Colloid and Interface Science; 209:172–184. https://doi.org/10.1016/j.cis.2014.04.002
  39. Zhao, H. and Lang, Y. (2018). Adsorption behaviors and mechanisms of florfenicol by magnetic functionalized biochar and reed biochar. Journal of the Taiwan Institute of Chemical Engineers, 88: 152-160. https://doi.org/10.1016/j.jtice.2018.03.049
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